biochar vs hugelkultur
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Environmental Comparison of Biochar and Activated Carbon for Tertiary Wastewater Treatment
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Phd Thesis On Biochar
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An Overview of the current Biochar and Activated Carbon Markets
Special to The Digest
Biochar is an emerging market; growing rapidly, still in its infancy, but with gigaton market potential when we, as in humanity, start addressing the climate crisis. Activated carbons are a mature market of about one million tons annual production, which is growing slowly. They are basically like fraternal twins; they have a lot in common, they share the same world, and they are different.
First, let’s explain the basic difference between THREE materials: activated carbon, charcoal and biochar. Activated carbon, also known as activated charcoal and several other ‘active/activated source-material’ names, all come down to the implication of the modifier ìactivatedî. When used in conjunction with adsorbents, ‘activated’ refers to a small set of processing techniques that increase the internal microporosity of the original carbon-rich source material. All ‘activation’ processes remove individual carbon atoms and create individual nooks and crannies in the carbon-rich material, which are the adsorption sites. The key to activated carbon is that it is optimized for specific adsorption application (water, vapor, certain adsorbates, etc.) and the adsorption capacity is packed into as dense a material as possible to minimize the volume of adsorbent necessary. In the end, activated carbon is an adsorbent ñ intended to remove something, typically organic compounds, from either vapor or liquid streams.
In contrast, Charcoal is a fuel that is used for cooking and other heat generating applications and created by heating biomass, typically wood, under conditions of limited oxygen. In general, charcoal burns hotter and with less smoke than the starting biomass, and also can convert mineral ores to the corresponding metals, inspiring a series of ages: bronze, iron, etc.
Biochar is made in the same manner as charcoal, but it is intended for utilization as an adsorbent and/or a soil amendment. Basically, the key is the end use of the material. It is charcoal if it is intended to be used as a fuel; hence it is manufactured with optimal fuel properties. In contrast, if the intended use is adsorption or as a soil amendment, then it is manufactured to a different set of properties and labeled biochar. As a result, biochar shares properties with activated carbon and charcoal, but has a few unique features that distinguish it from both.
While biochar shares adsorption properties with activated carbon, it also exhibits a significant amount of ion exchange capacity, a property that is minimal or absent in traditional activated carbons. The ion exchange property, which is usually measured and reported as ‘cation exchange capacity’, is due to residual carboxylic acid functionalities on the biochar graphitic backbone. Since activation removes any residual side chain aliphatic groups, activated carbons have reduced ionic interactions.
The other big differences between biochar and activated carbons are bulk density and mechanical hardness. Activated carbon is intended for applications where packing as much adsorption capacity into a fixed volume is paramount, like gas masks and fixed-bed adsorbers. In addition, activated carbon can be regenerated and reused in many applications, so mechanical hardness (also known as the lack of friability) allows the carbon to be moved without falling apart or breaking down in particle size.
If one combines the lower adsorption per unit weight of biochar with the lower bulk density, the resulting adsorption capacity on a volume basis is 1/6th to 1/12th that of high quality activated carbons. For this reason, biochar is typically used in applications where the material is spread out on the ground, so low density is not a disadvantage. In fact, in soil applications, where an important property is the ability to capture excess precipitation and retain it, the low density of biochar translates into additional voids that can fill when it rains.
Biochar is a material that is preferred when several of its unique properties can be exploited in the same application. The unique properties of biochar include low density (providing additional voidage and aeration in the soil), significant adsorption and cation exchange capacity, and the ability to promote living microbiology in the soil, enhancing the ìSoil Food Webî. Combining these properties leads to a predictable selection criteria for when to consider activated carbons versus biochar.
As noted earlier, activated carbon is intended and optimized for adsorption applications, and is available in many physical forms and grades that are specialized to the end use. The market has been growing steadily for the past 50 years, driven by specific purification processes in some industries and many applications involving removal of organic compounds from air and water streams prior to discharge into the environment. Indeed, most of the activated carbon demand has been created by a series of environmental regulations that have been enacted over the years, including the Clean Water Act and the Clean Air Act.
The current world production of activated carbon products is approximately one million tons per year, with most production in Tropical and Asian countries. The majority of activated carbon production is exported to developed countries in North America and Europe, where it is used in environmental and processing applications. The activated carbon marketplace is dominated by a relatively small number of international companies that have both production and marketing capabilities.
Over the past few years, the developed countries have been enacting new regulations requiring the removal of trace mercury from industrial emissions, principally impacting the coal-based electric power industries in North America and Europe. This has created an additional market for specialized powdered activated carbons that serve to capture mercury from the flue gases of power plants. The potential market demand for these MATS = Mercury and Air Toxics Standards activated carbon is several hundred thousand tons per year if the entire industry used the technology, but the combination of aging coal plants and cheap natural gas has resulted in significantly lower actual market requirements for mercury-capture activated carbons.
Mercury capture is one of very few market applications where biochar products might complete with traditional activated carbon products, with the other being those remediation applications where soil decontamination due to legacy pesticides or ordnance residues are preventing significant plant growth. In the mercury marketplace, biochar is at a disadvantage due to the presence of established suppliers from the activated carbon producers. In contrast, in remediation, biochar has the advantage that it can provide the initial detoxification requirements, followed by providing the added benefits of improving the soil as a growing medium for all forms of vegetation.
The biochar marketplace is nascent and suffering from ìthe chicken or the egg syndrome. To date, there have not been sufficient reliable suppliers of biochar products to allow the demonstration of the at-scale value propositions in specific biochar markets. Thus, the issue of how cost-effective is biochar in reducing water and fertilizer requirements in specific markets such as corn cultivation is basically unresolved, although credible studies are accumulating in the literature and within individual industrial demonstrations. Furthermore, in the absence of specific market opportunities that demonstrate the value of biochar, financing biochar production capacity is stymied. The development gridlock is slowly being resolved and rapid growth in biochar capacity and adoption is anticipated over the next decade.
There are some external drivers that are also promoting biochar adoption, including atmospheric carbon dioxide levels and concerns driven by consequences of climate change. Since biochar is produced from biomass that was created from carbon derived from carbon dioxide from the atmosphere as the plant grew, the carbon in biochar is viewed as ‘carbon-negative’. As such, it represents carbon removed from the air and converted into a form that will remain in the soil (and out of the atmosphere) for centuries or longer.
Unfortunately, to date, the direct financial incentives for sequestering carbon dioxide have been insufficient to significantly stimulate biochar production. With the adoption of the Paris Climate Accord, biochar has become recognized as one of the most viable and accessible methods for reducing a nationís carbon footprint and meeting future emission reduction obligations. This trend will play itself out in many versions in individual nationís public policies for managing the requirements of utilizing fossil fuels and achieving reduced overall climate impact goals.
Frankly, it is impossible to predict how the climate driver will or will not stimulate the future biochar production and utilization patterns. Additional, and equally powerful, drivers for the adoption of biochar are the documented improvements in water requirements in agriculture due to improved moisture retention and management by biochar-enhanced soils. With the improved water retention, the concurrent phenomenon of loss of soluble soil nutrients by leaching, when excess precipitation extracts nutrients out of the soil, is suppressed. It is the combined improvements in water and fertilizer efficiency by an existing growing method, coupled with the potential benefits of enhanced soil health due to improved soil microbiology, that create a powerful economic argument for the widespread adoption of biochar.
However, only time will tell how it will all play out.
Hugh McLaughlin is a member of Lee Enterprises Consulting. Lee Enterprises Consulting is the worldís premier bioeconomy consulting group, who have consultants and experts worldwide, including in the technologies discussed in this report.† The opinions expressed in the report are those the author, and do not, necessarily, express the views of Lee Enterprises Consulting.
Hugh has a B.S. in Chemistry from Harvey Mudd College, an M.S. in Chemical Engineering from the USC, and a Ph.D. in Chemical Engineering from Rensselaer Polytechnic Institute. He is a registered professional engineer in Massachusetts. Hugh is a recognized technical/technology expert in biochar and activated carbon, having designed and commercialized patented technologies for their production. He is a leading authority on biochar properties and characterization.
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phd thesis on biochar
phd thesis on biochar
The fd and ps kits yielded very similar results for the fungal community profiles ( ) and indicated that the addition of biochar (ewb and ssb) modified the native fungal community (sc). However, there are very few studies describing the effect of biochar on native soil microbial communities. Rillig mc, mummey dl (2006) mycorrihizas and soil structure.
Accurate and sensitive quantitation of nucleic acids, even at low concentrations comparison of the qubit im quantitation platform with spectrophotometry. Baldrock ja, smernick rj (2002) chemical composition and bioavailability of thermally altered pinus resinosa (red pine) wood. The results obtained for the dna isolated with the zr kit may be related to the lower amount of dna recovered after extraction, which may have interfered with the pcr-dgge profiles ( ).
Chattoraj dk, mitra a (2009) adsorption of dna at solid-water interfaces and dna -surfactant binding interaction in aqueous media. Observations on microbial dynamics lead to the conclusion of a possible improved resource use due to co-location of various resources in and around biochars. Dna, and lower ratios indicate humic acid and protein contamination, respectively (ning the amplification of specific regions of the gene encoding the 16s rrna was performed using the primers u968 gc (5 cgc ccg ccg cgc gcg gcg ggc ggg gcg ggg gca cgg ggg gaa cg cga aga acc tta c 3) and l1401 , 1997). Each dna extraction method resulted in different clusters for the bacterial community ( ) showed that bacterial communities of the ewb and sc treatments were similar.
These methods have advantages over classical protocols because only 1-10 of the microorganisms in an environmental sample can be cultured (hugenholtz , 2009). No evidence exists so far for direct negative effects of biochars on plant roots. This result was not observed when the fd kit ( ) was used for the dna extraction.
The use of molecular biology methods to analyse microbial communities from environmental samples requires reproducible and efficient strategies for dna extraction. The ps kit resulted in the lowest level of humic acids (it extracted 36 times less humic acids than the fd kit). Fd kit resulted in a higher amount of humic acids co-extracted together with the dna (about three times more than with the zr kit).
Milli-q water in a final volume of 25 l. Occasionally observed decreases in abundance of mycorrhizal fungi are likely caused by concomitant increases in nutrient availability, reducing the need for symbionts. The similarities between the banding patterns in the dgge profiles were calculated based on the presence and absence of bands and were expressed as similarity coefficients. In this study, the purity of the dna was assessed spectrophotometrically by calculating the a260a230 and a260a280 ratios to evaluate the levels of humic acid contamination and protein impurities, respectively.
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Phd thesis on biochar
These are only a few ways to save on your essay. The APECS project wants to answer some specific questions about biochar What is biochar really capable of. Can it turn digestate into more. My favorite hobby essay in urdu. Can it turn sandy sites into fruitful soils. And, not to be forgotten, can it turn struggling farmers into successful pioneers. Several novel reactor types are being tested. A major milestone of APECS is to develop biochar that is specifically optimized for the improvement of sandy soils. Jrgen Kern and members of his research team with soil incubation bottles designated for gas chromatography.
Three certified instructors to teach Korean Natural Farming workshop
Oct 23, 2016
The Hawai’i Farmers Union United, Hawai’i Farmers Union Foundation and the state Department of Agriculture will present a two-day Korean Natural Farming workshop from 10 a.m. to 5 p.m. Nov. 5 and 6 at Maui Tropical Plantation in Waikapu.
Korean Natural Farming focuses on living soil and indigenous microorganisms, and maximizes the use of on-farm resources, recycles farm waste and minimizes external inputs while fostering soil health and sustainable agriculture.
In this hands-on workshop, participants will learn how to improve soil health and productivity by using the ancient art of nutrient extracts and fermentation. They will experience how to make various Korean Natural Farming inputs such as indigenous microorganism soil inoculant, fish amino acids, water-soluble calcium and Oriental herbal nutrient.
The workshop will include a farm site visit to explore Korean Natural Farming protocols being implemented.
The cost for Hawai’i Farmers Union United members is $100 ($150 for nonmembers, which will include an annual membership to HFUU) for the two-day workshop. Cost of registration includes registrants receiving $100 worth of inputs to take back to their farm or garden to apply. The workshop also includes lunch by Maui Tropical Plantation on both days.
Registration will close after the first 50 paid entries, and attendees are encouraged to wear comfortable clothing that one might garden in.
Korean Natural Farming is applicable to many types and scales of farming — from backyard vegetable gardening to larger-scale farm or livestock operations. Participants will leave the workshop equipped with the knowledge to implement Korean Natural Farming practices on their own farm or garden.
The workshop will be taught by three Korean Natural Faming certified instructors:
• Seth Raabe is the farm manager of Mahele Farm in Hana, a community farm that serves as an educational, sustainable and healthy food resource for the isolated East Maui region. He is certified in Korean Natural Farming.
• Vincent Mina co-owns and operates Kahanu Aina Greens in Wailuku. Last year alone, this family farm produced 21,000 pounds of food within just 2,000 square feet of space using Korean Natural Farming techniques and plant-based compost. Mina is also the statewide president of the Hawai’i Farmers Union United. He is certified in Korean Natural Farming and JADAM Organic practices.
• Ricky Apana is the owner of Maui Bio Char and is active in making bio char and IMO-3 (a Korean Natural Farming amendment) in bulk. He is also certified in Korean Natural Farming and JADAM Organic practices.
To register or for details, visit hfuuhi.org and select “Events.”
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Biochar-stimulated plant performance is strongly linked to microbial diversity and metabolic …
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Fig. S1 Schematic diagram of experimental procedure.
Fig. S2 Bacterial class composition.
Fig. S3 Effect of biochar soil amendment on root‐associated microbial community composition.
Table S1 Characteristics of the dune sand used in this study
Table S2 Tomato plant physiological parameters
Table S3 Tomato plant metabolites
Table S4 Bacterial taxa displaying significant differences in relative abundance in Experiment I
Table S5 Statistical analyses of beta diversity generated from Experiments I and II
Table S6 Bacterial taxa displaying significant differences in relative abundance in Experiment II
Table S7 Putative GC‐MS identifications of compounds in the Biochar EUC‐350 extract
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Biochar: The Sequestration Technology for Carbon Prices above $400 / ton
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New biochar model scrubs carbon dioxide from the atmosphere
An economically viable model to scrub carbon dioxide from the atmosphere has been developed to thwart runaway, point-of-no-return global warming. The researchers propose using a “bioenergy-biochar system” that removes carbon dioxide from the atmosphere in an environmental pinch, until other removal methods become economically feasible and … Read entire story.
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